不同造孔剂对CaCu3Ti4O12多孔陶瓷介电性能的影响

以碳粉和蛋清作为造孔剂,利用固相法制备CaCu3Ti4O12(CCTO)多孔陶瓷.研究了造孔剂含量对CCTO多孔陶瓷体积密度、显微结构和介电性能的影响.结果表明,随着碳粉含量增加,体积密度先增加后减小;而随着蛋清含量增加,体积密度先减小后增加.和碳粉相比,蛋清加入制备的试样具有较小、较均匀的孔隙.当频率大于331.5KHz时,添加碳粉可以降低介电损耗.当频率大于4KHz时,添加碳粉介电常数有所下降.当频率大于2KHz时,添加蛋清可以增大介电损耗,但是增加幅度较小.添加蛋清可以增大介电常数.     

Keggin型配合物[(CH_2)_5NH_2]_4SiMo_(12)O_(40)催化合成香兰素1,2-丙二醇缩醛的研究

以自制的Keggin型配合物[(CH2)5NH2]4SiMo12O40为催化剂,香兰素和1,2-丙二醇为原料,苯为带水剂,制备香兰素1,2-丙二醇缩醛.对物料配比、催化剂用量和反应时间等因素经行考察.表明:Keggin型配合物[(CH2)5NH2]4SiMo12O40具有较好的催化效果,且可重复利用.最佳反应条件为:香兰素15.2 g(0.1 mol),n(香兰素)n(1,2-丙二醇)n((CH2)5NH2]4SiMo12O40)=1 1.50 0.05,苯20 mL,反应时间2.0 h条件下,产品收率达到88%以上.     

基于STC单片机的GPS定位显示系统设计

全球定位系统（ GPS）能够全天候、全方位的为海陆空用户提供连续的、高精度的三维坐标、三维速度和时间等信息。本设计以STC12C5A60S2单片机为核心进行硬件电路设计,采用集成GPS信号接收模块ATK-NEO-6M接收GPS卫星信号,单片机接收该数据并进行数据处理,在德飞莱TFT2．4液晶显示屏上显示出相应信息。应用C语言进行软件设计,实现GPS信号的提取、显示及基本的控制操作等,给出了软件流程图。     

新型锦纶油剂的配制及性能测试

通过使用七种表面活性剂复配方法,采用对比试验得到了新型锦纶油剂。应用45°倾斜法、防护系数UPF评定法、动摩擦系数μk测定、体积比电阻ρv测定、残油率测定、精炼度A测定、湿抱合力测定等实验方法测试,新型锦纶油剂的阻燃整理性、防紫外线性、抗静电性、稳定性、防水整理性、精炼性、平滑性各项性能实验结果,都比同类sp-3上油浆丝、Y-上油浆丝等优越。从而更好地防止织物在制造过程中产生自燃、静电、起毛、落浆等弊病。     

基于流固耦合的尼龙网流场特性及变形分析

考虑到柔性网衣在水流作用下易发生变形,会造成网箱有效体积减小并伴随网衣撕裂风险,因此研究网衣周围流场变化及网衣变形特性具有重要意义。基于剪应力SST k-ω湍流模型,结合ANSYS Workbench的单向流固耦合(Fluid-Solid Interaction, FSI)方法,将网衣所受压力作为输入载荷施加在平面网表面,研究在不同流速、网衣密实度和攻角情况下平面尼龙无结网衣的流场特性,对大变形非线性网衣结构的有限元模型进行分析。结果表明基于FSI的单向耦合数值模拟用于平面网衣变形及流场特性分析具有可行性,网衣造成的流速降低现象在不同攻角条件下的差异较明显。得到网衣水动力系数在不同流速、网衣密实度和攻角下的变化情况,以及平面网的等效应力分布特点和变形随攻角变化的特性,发现从网衣中心网线至边缘位置网线处的应力由大逐渐变小,最终在网线固定端附近发现应力最大位置。     

Comparison of ISO 14902:2001 with AOCS Ba 12a-2020 for determining trypsin inhibitor activity in protein products

For measuring trypsin inhibitor activity (TIA), there are two major official methods: American Oil Chemists Society (AOCS) method Ba 12a-2020 and International Organization for Standardization (ISO) 14902:2001. The former was recently approved. The two methods differ in sample preparation, extraction, colorimetric assay systems and TIA calculations. In this study, the two methods were symmetrically compared using three unique sets of samples: assorted protein products of soybeans, pulses, and grains; soybeans boiled for varied durations; and soy white flakes toasted for varied durations. For given samples, significant differences existed in TIA measured by the two methods, resulting from effects related to the assay systems and TIA calculations, not from the difference in sample preparation and extraction. When the same trypsin was used, TIA (in mg trypsin inhibited/g sample) measured by the two methods were highly correlated (r = 0.9973, n = 27), giving an equation of y = 0.5464x − 0.4887, where y represents ISO values and x for AOCS values. The line connecting ratios of ISO/AOCS in TIA and AOCS values remained relatively flat around 0.53 but started to curve down when TIA approached the lowest. Furthermore, for the same samples, TIA values measured by the ISO method decreased with increasing specific activity of trypsin used, while AOCS values remained consistent, leading to decreasing ratios of ISO/AOCS. Therefore, accurate and direct comparison of the two methods was impossible. It could not be resolved by simply changing ISO method's calculations as hypothesized earlier. Regardless, for most samples, ISO values were roughly about 55% of AOCS values.     

Characterization of PA-12 specimens fabricated by projection sintering at various sintering parameters

Large area projection sintering (LAPS) promises to be a new method in the field of additive manufacturing. Developed in the Mechanical Engineering Department, University of South Florida, LAPS uses long exposure times over a broad area of powder to fuse into dense, reproducible materials. In contrast, LS, a common powder-based additive manufacturing, uses a focused beam of light scanned quickly over the material. Local regions of concentrated high-energy bursts of light lead to higher peak temperatures and differing cooling dynamics and overall crystallinity. The mechanical properties of laser sintered specimens suffer because of uneven particle fusion. LAPS offers the capacity to fine-tune fusion properties through enhanced thermodynamic control of the heating and cooling profiles for sintering. Further research is required to identify the relationship between LAPS build settings and part properties to enable the fabrication of custom parts with desired properties. This study examines the influence of LAPS sintering parameters on chemical structures, crystallinity, mechanical, and thermal properties of polyamide-12 specimens using powder X-ray diffraction, Fourier transform infrared spectroscopy, differential scanning calorimetry, small-angle X-ray scattering, scanning electron microscopy, and microhardness testing. It was observed that higher crystallinity was imparted to specimens that were sintered for a shorter time and vice versa.     

LY12铝合金在模拟酸雨溶液中的阻抗谱研究

利用电化学阻抗谱和极化曲线方法 ,研究了模拟酸雨溶液 pH值对LY12铝合金腐蚀行为的影响 .结果表明 ,当模拟酸雨溶液 pH小于 3 1时 ,LY12铝合金的腐蚀电位随pH值的升高而变负 ;当溶液 pH大于 3 4时 ,LY12铝合金的腐蚀电位随 pH值升高而变正 .在 pH小于 3 4的模拟酸雨溶液中 ,LY12铝合金的表面膜发生溶解 ,随着浸泡时间延长 ,膜厚度降低 ,膜阻抗降低 ,LY12铝合金的腐蚀速率升高 .而在 pH大于 3 8溶液中 ,LY12铝合金的表面膜厚度基本不随浸泡时间发生明显变化 ,随浸泡时间增加 ,膜阻抗增大 ,LY12铝合金的腐蚀速率降低 .从铝合金表面膜特性和离子吸附及腐蚀产物等方面 ,对实验结果进行了讨论     

Novel accelerated corrosion test for LY 12CZ and LC4CS aluminum alloys

A new accelerated corrosion test--comprehensive environmental test （CET） was developed in order to estimate the outdoor corrosion of aluminum alloys in marine environment. The environmental characteristics in CET were studied by atmospheric corrosion monitor （ACM）, and the morphology of corrosion product was observed by SEM. The correlation between the accelerated corrosion tests and outdoor exposure was discussed. The results show that the anti-corrosion ranking for LY12CZ, LC4CS, clad LY12CZ, and clad LC4CS in CET is the same as that of the alloys exposed outdoor, and ACM study shows that CET demonstrates the .same environmental characteristics as that exposed outdoor. CET is a more accurate accelerated corrosion test, and a mathematical relation was obtained to describe the relation between CET and outdoor test.     

压缩机叶轮用钢——X12Cr13锻件工艺研究

通过对X12Cr13钢中奥氏体与铁素体的相匹配关系的研究,确定出该钢种合理的化学成分和合理的加热及热处理制度,解决了该钢在轧制、锻造等压力加工过程中易产生裂纹的问题。